Yes! Find the person you are looking to video chat with in the People tab on the right side of the screen. Ensure that the tabs haven’t been collapsed if you don’t see the People tab. Click on the name of the person you want to chat with and then click on the Invite to Video Chat button underneath their name. This will generate a link that will take you and the other person out of any video sessions you happen to currently be in and into a private one-on-one video chat.